Neil,
A couple of points/questions

1) Where have you placed the wideband in the exhaust system?
2) An AFR of 13.0:1 seems quite lean to me, although my experience is with Japanese turbo engines (Subaru) - where at full boost I would expect to see around 10.5:1, although we are using some of the extra fuel to cool the inlet charge (especially in high boost applications), and they are detonation prone.
3) Are you using any form of detonation detection, particularly during mapping?
One concern of using a single wideband is ensuring that the AFR's for each cylinder are equal, as you are currently measuring an average of all 4. Maybe having the injectors flow tested for equal flow at say 50% duty cycle maybe in the interests of longevity, along with a good old 'plug chop' when out testing.
Another Neil - who is also planning on a Duratech Caterham - so get yours sorted!